The gradient color used for emphasizing the upper portion of the glossy effect when the control is in pressed state.
Below the button with its default value on the left and with the VistaColorGlossyEmphUpperPressed property set to yellow on the right:
 
The gradient effect of this color can be enhanced/reduced through the VistaOpacityGlossyEmphUpperPressed property.
For further details about settings for the Vista's Aero style, see the How to manage colors of Vista's Aero style tutorial.
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